ASTM D6888-2009 用气体扩散分离和电流计探测法对有效氰化物进行配位位移和流量注入分析的标准试验方法

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【英文标准名称】:StandardTestMethodforAvailableCyanidewithLigandDisplacementandFlowInjectionAnalysis(FIA)UtilizingGasDiffusionSeparationandAmperometricDetection
【原文标准名称】:用气体扩散分离和电流计探测法对有效氰化物进行配位位移和流量注入分析的标准试验方法
【标准号】:ASTMD6888-2009
【标准状态】:现行
【国别】:美国
【发布日期】:2009
【实施或试行日期】:
【发布单位】:美国材料与试验协会(US-ASTM)
【起草单位】:D19.06
【标准类型】:(TestMethod)
【标准水平】:()
【中文主题词】:
【英文主题词】:amperometry;availablecyanide;cyanide;cyanideamenabletochlorination;flowinjectionanalysis;freecyanide;gasdiffusionmembrane;ligandexchange;silverelectrode;weakaciddissociablecyanide;Amperometrictitration;Cyanides;Flowinj
【摘要】:Cyanideandhydrogencyanidearehighlytoxic.Regulationshavebeenestablishedtorequirethemonitoringofcyanideinindustrialanddomesticwastesandsurfacewaters.Thistestmethodisapplicablefornaturalwater,salinewaters,andwastewatereffluent.Themethodmaybeusedforprocesscontrolinwastewatertreatmentfacilities.1.1Thismethodisusedtodeterminetheconcentrationofavailableinorganiccyanideinanaqueouswastewateroreffluent.Themethoddetectsthecyanidesthatarefree(HCNandCN-)andmetal-cyanidecomplexesthatareeasilydissociatedintofreecyanideions.Themethoddoesnotdetectthelesstoxicstrongmetal-cyanidecomplexes,cyanidesthatarenotx201C;amenabletochlorination.x201D;1.2TotalcyanidecanbedeterminedforsamplesthathavebeendistilledasdescribedinTestMethodsD2036,TestMethodA,TotalCyanidesafterDistillation.Thecyanidecomplexesaredissociatedandabsorbedintothesodiumhydroxidecapturesolution,whichcanbeanalyzedwiththistestmethod;therefore,ligandexchangereagentsfromSections8.12and8.13wouldnotberequiredwhendeterminingtotalcyanideafterdistillation.1.3Thisprocedureisapplicableoverarangeofapproximately2to400x03BC;g/L(partsperbillion)availablecyanide.Higherconcentrationscanbeanalyzedbydilutionorlowerinjectionvolume.1.4ThevaluesstatedinSIunitsaretoberegardedasstandard.Nootherunitsofmeasurementareincludedinthisstandard.1.5Thisstandarddoesnotpurporttoaddressallofthesafetyconcerns,ifany,associatedwithitsuse.Itistheresponsibilityoftheuserofthisstandardtoestablishappropriatesafetyandhealthpracticesanddeterminetheapplicabilityofregulatorylimitationspriortouse.SpecifichazardstatementsaregiveninNote2andSection9.
【中国标准分类号】:N12
【国际标准分类号】:17_120_10
【页数】:7P.;A4
【正文语种】:英语